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Hafez, Islam; Yang, Han-Seung; Liew, Feng Jin; Schilling, Jonathan S; Tze, William_T Y (, ACS Sustainable Chemistry & Engineering)
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Rahman, Md Musfiqur; Hafez, Islam; Tajvidi, Mehdi; Amirbahman, Aria (, ACS Sustainable Chemistry & Engineering)
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González-Ugarte, Alina S.; Hafez, Islam; Tajvidi, Mehdi (, Scientific Reports)Abstract Hybrid nanocellulose-based foams are a desirable class of low-density and porous materials for their potential in many applications. This study aims at characterizing and understanding the structure-properties relationship of four foam formulations prepared from combinations of cellulose nanofibrils (CNF), cellulose nanocrystals (CNC), and kaolin-microfibrillated cellulose composite. All the foams were crosslinked with a polyamide-epichlorohydrin crosslinker (Polycup) to impart stability under wet conditions without additional functionalization. Foams containing 25 wt% kaolin exhibited excellent shape recovery promoted by a higher load of crosslinker (5 wt%), and superior compressive properties. The addition of CNC at 33.3 wt% and 50 wt% did not seem to enhance the properties of the foam and also reduced the specific surface area. A preliminary comparative study between the four tested formulations was conducted to assess the feasibility of the foam as an adsorbent of methylene blue dye.more » « less
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